Publication Summary  (May 2012)

h-Index:   12      ||       Impact Factor Points (IFP):    113.08     ||     IFP/yr (avg):   14.1

Postdoctoral Publications (#citations)

1) M. J. Rose, R. M. Mercado, B. S. Brunschwig, H. B. Gray. Perfluorinated Cobaloximes: Electrocatalytic H2 Generation with overpotentials comparable to Pt in MeCN. In preparation.

2) M. J. Rose, D. E. Bellone and H. B. Gray. Structural , Magnetic and Spectroscopic Characterization of an High Spin Iodo Co(I) Complex derived from a Tripodal Phosphine. Submitted.

3) M. J. Rose, J. R. Winkler and H. B. Gray. Hydrogen Evolution at from Fluorinated Diglyoxime Iron Complexes at Low Overpotentials. J. Am. Chem. Soc. 2012, 134, 8310-8313. (0)

4) L. E. O'Leary, M. J. Rose, T. X. Ding, E. Johansson, B. S. Brunschwig and N. S. Lewis. Heck Couplings of Small Molecules to Mixed Methyl/Thienyl Monolayers at Low Defect Density Si(111). Submitted.

5) M. J. Rose, J. R. Winkler and H. B. Gray. Four-Iron Cluster and a Buckled Macrocycle Complex from Reduction of [(dmgBF2)Fe(L)2] (L=MeCN, tBuiNC). Inorg Chem. 2012, 51, 1980-1982. (0)

6) Q. Dong, M. J. Rose, W.-Y. Wong and H. B. Gray. Dual Coordination Modes of Ethylene Linked NP2 Ligands with Cobalt(II) and Nickel(II) Iodides. Inorg. Chem. 2011, 50, 10213-10224. (0)

Graduate Publications (#citations)

1) M. J. Rose, N. M. Betterley, A. Oliver, and P. K. Mascharak. Binding and Photorelease of Nitric Oxide (NO) to a Synthetic Model of Iron-Containing Nitrile Hydratase (Fe-NHase). Inorg. Chem. 2010, 49, 1854-1864. (6)

2) M. J. Rose, A. K. Patra, M. M. Olmstead and P. K. Mascharak. Structural and Spectroscopic Evidence for Linkage Isomerism of Bound Nitrite in a {Fe-NO}6 Nitrosyl derived from a Tetradentate Dicarboxamide Ligand: More Parallels between Heme and Non-heme Systems. Inorg. Chim. Acta 2010, 363, 2715. (2)

3) N. Fry, M. J. Rose, David L. Rogow, C. Nyitray, Manpreet Kaur and P. K. Mascharak. Ruthenium Nitrosyls Derived from Tetradentate Ligands containing Carboxamido-N and Phenolato-O Donors: Syntheses, Structures, Photolability and Time-Dependent Density Functional Studies. Inorg. Chem. 2010, 49, 1487. (16)

4) M. J. Rose, N. M. Betterley, P. K. Mascharak. Thiolate S-Oxygenation Controls Nitric Oxide (NO) Photolability of a Synthetic Iron Nitrile Hydratase (Fe-NHase) Model Derived from Mixed Carboxamide/Thiolate Ligand. J. Am. Chem. Soc. 2009, 131, 8340-8341. (8)

5) M. J. Rose, P. K. Mascharak. Photosensitization of Ruthenium Nitrosyls to Visible Light with an Isoelectronic Series of Heavy-Atom Chromophores: Experimental and DFT Studies on the Effects of O-, S- and Se-Substituted Coordinating Dyes. Inorg. Chem. 2009, 48, 6904-6917. (18)

6) N. Fry, M. J. Rose, C. Nyitray, and P. K. Mascharak. Metal Nitrosyls with Phosphine Ligation: Unexpected Ligand Oxidation and Ring Nitration. Inorg. Chem. 2008, 47, 11604-11610. (3)

7) M. J. Rose and P. K. Mascharak. A Photosensitive {Ru-NO}6 Nitrosyl Bearing Dansyl Chromophore: Novel NO Donor with a Fluorometric On/Off Switch. Chem. Commun. 2008, 3933-3935. (16)

8) M. J. Rose, N. Fry, R. Marlow, L. Hinck and P. K. Mascharak. Ruthenium Nitrosyls bearing Coordinated Fluorophores as NO Donors: a Novel Mode of Fluorometric Delivery of NO to Cells with Visible Light. J. Am. Chem. Soc. 2008, 130, 8834-8846. (64)

9) M. J. Rose, P. K. Mascharak. Photoactive Ruthenium Nitrosyls: Effects of Light & Potential as Biological NO Donors. Coord. Chem. Rev. 2008, 252, 2093-2114. (74)

10) M. J. Rose and P. K. Mascharak. Fiat Lux: Selective Delivery of High Flux of Nitric Oxide (NO) to Biological Targets using Photosensitive Metal Nitrosyls. Curr. Opin. Chem. Biol. 2008, 12, 238-244. (46)

11) M. J. Rose, M. M. Olmstead and P. K. Mascharak. Photosensitization via Dye Coordination: A New Strategy to Synthesize Metal Nitrosyls that Release NO under Visible Light. J. Am. Chem. Soc. 2007, 129, 5342-5343. (41)

12) M. J. Rose, M. M. Olmstead and P. K. Mascharak. Photoactive Ruthenium Nitrosyls Derived from Quinoline- and Pyridine-based Ligands: Accelerated Photorelease of NO due to Quinoline Ligation. Polyhedron 2007, 26, 4713-4718. (12)

13) M. J. Rose, A. K. Patra, E. A. Alcid, M. M. Olmstead and P. K. Mascharak. Carboxamido and Schiff Base Ruthenium Nitrosyls: Isoelectronic Complexes with Markedly Different Properties of Photolability and Reactivity. Inorg. Chem. 2007, 46, 2328-2338. (32)

14) M. J. Rose,* I. Szundi,* I. Sen, A. A. Eroy-Reveles, P. K. Mascharak and Ó. Einarsdóttir. New Approach for Studying Fast Biological Reactions Involving Nitric Oxide: Generation of NO Using Photolabile Ruthenium and Manganese NO Donors. Photochem. Photobiol. 2006, 82, 1377-1384. (27)  (*equal authorship)

15) D. C. Swinney, M. J. Rose, A. Y. Mak, I. Lee, L. Scarafia and Y. Xu. Bi-Substrate Kinetic Analysis of an E3–Ligase–Dependent Ubiquitylation Reaction. Methods Enzymol. 2005, 399, 323-333. (1)

16) A. K. Patra, M. J. Rose, M. M. Olmstead and P. K. Mascharak. Reactions of Nitric Oxide with a Low-spin Fe(III) Center Ligated to a Tetradentate Di-carboxamide N4 Ligand: Parallels between Heme and Non-Heme Systems. J. Am. Chem. Soc. 2004, 126, 4780-4781. (28)

17) A. K. Patra, M. J. Rose, K. A. Murphy, M. M. Olmstead and P. K. Mascharak. Photolabile Ruthenium Nitrosyls with Planar Di-carboxamide Tetradentate N4 Ligands: Effects of In-plane and Axial Ligand Strength on NO Release. Inorg. Chem. 2004, 43, 4487-4495. (68)

18) M. J. Rose, I. Lee, T. R. Chapman and D. C. Swinney. Pharmacological Characterization of Clinical Anti-Cholinergic Drugs at M1–M5 Receptor Sub-types. Mol. Biol. Cell. 2002, 443, 79A.* (0)

19) D. C. Swinney, M. J. Rose, I. Lee, A. Y. Mak. The Mono-ubiquitination of IkBa S32/36E in vitro Shows a Random Bi-Bi Kinetic Mechanism with Respect to IkBa-ee and E2UBCH7. FASEB J. 2001, 15, A26.* (0)

*denotes abstract of work performed in industry (not included in Impact Factor Score)